Product ID:BUTAREZ CATALYST
MSDS Date:03/31/1990
FSC:6850
NIIN:00N067018
MSDS Number: CBWLF

PHILLIPS 66 CO

758 ADAMS BLVD 4TH AND KEELER
BARTLESVILLE, OK 74004
US

Emergency Phone: 918-661-3865; 918-661-8118

Info Phone: 918-661-8327

Cage: GO225

PHILLIPS PETROLEUM CO

BARTLESVILLE, OK 74004 US

Telephone: 800-234-6603

Cage: 46935

ETHANE, 1,1'-OXYBIS-; (ETHYL ETHER) (CERCLA)

CAS: 60-29-7

RTECS: KI5775000

Fraction By Weight: 25%

OSHA PEL 400 PPM

ACGIH TLV: 400PPM/500STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

NAPHTHALENE, METHYL-; (METHYLNAPHTHALENE)

CAS: 1321-94-4

RTECS: QJ9625000

Fraction By Weight: 10%

OSHA PEL N/K

ACGIH TLV: N/K

POLYMER, INCLUDING INGREDIENTS 4 AND 5

RTECS: 9999999ZZ

Fraction By Weight: <60%

OSHA PEL N/K

ACGIH TLV: N/K

1,3-BUTADIENE (SARA 313) (CERCLA)

CAS: 106-99-0

RTECS: EI9275000

Fraction By Weight: >1%

OSHA PEL 1000 PPM

ACGIH TLV: 2 PPM; A2

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LITHIUM

CAS: 7439-93-2

RTECS: OJ5540000

Fraction By Weight: >1%

OSHA PEL N/K

ACGIH TLV: N/K

INFO SHOWN IN CTL MEASURES IS BASED UPON GEN

RTECS: 9999999ZZ

USES/CNDTNS EXIST, IT IS SUGGESTED THAT EXPERT

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:BIOLOGICAL EFTS HAVE NOT BEEN
VERIFIED BY TESTING. EYE:MAY CAUSE TRANSITORY IRRIT FROM LIQ/HIGH
VAP CONC. SKIN:MILD IRRIT EXPECTED FROM BRIEF EXPOS W/DRYING &
CRACKING RSLTING FROM RPTD & PRLNGD EXPOS. INHAL:HIGH VAP CONC MAY
BE IRRIT TO NOSE, THROAT & UPPER RESP SYS. OVEREXP MAY RSLT IN
BLURRED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BUTADIENE (1,3):IARC MONOGRAPHS ON EVAL
OF CARCIN RISK OF CHEMS TO MAN, VOL 54, PG 237, 1992:GROUP 2A. NTP
7TH (SUPDAT)
Effects of Overexposure:HLTH HAZS:VISION, NAUS, PRICKLING & DRYNESS OF
MOUTH, THROAT & NOSE, FATG, HDCH, VERTIGO, APPETITE LOSS,
EXCITATION, UNCON & RESP PARALYSIS. INGEST:MAY CAUSE GI UPSET.
COULD BE TOX IF LG AMTS SWALLOWE D. CHRONIC:INGEST OF LITHIUM CAN
PRDCE GI EFTS, CNS TOX & TOX DERM. LITHIUM TOX IS SODIUM DEPENDENT.
TARGET (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:FLUSH W/RUNNING WATER FOR @ LST 15 MIN. IF IRRIT
DEVELOPS, SEEK MED ATTN. SKIN:WASH W/SOAP & WATER. IF IRRIT
DEVELOPS, SEEK MED ATTN. INHAL:REMOVE FROM EXPOS. IF BRTHG IS
DFCLT, GIVE OXYG. IF BRTH G CEASES, ADMIN ARTF RESP FOLLOWED BY
OXYG. IF ILLNESS/ADVERSE SYMPS DEVELOP, SEEK MED ATTN. INGEST:GIVE
2 GLASSES OF WATER & INDUCE VOMIT. IF ILLNESS/ADVERSE SYMPS
DEVELOP, SEEK MED ATTN.

Flash Point:<-30F,<-34C
Extinguishing Media:HALON.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . EVACUATE AREA OF ALL UNNEC PERS. SHUT OFF
SOURCE IF POSS. WATER MUST NOT BE USED.
Unusual Fire/Explosion Hazard:CARBON OXIDES FORMED WHEN BURNED. HIGHLY
FLAM VAPS WHICH ARE HVR/AIR MAY ACCUM IN LOW AREAS &/OR SPREAD
ALONG GROUND AWAY FROM HNDLG SITE. MAY FORM (SUPP DATA)

Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR PROT
EQUIP &/OR GARMENTS DESCRIBED IN CTL MEASURES IF EXPOS CNDTNS
WARRANT. SHUT OFF SOURCE, IF POSS & CNTN SPILL. PROT FROM IGNIT.
KEEP OUT OF WATER SOURCES & SE WERS. ABSORB IN DRY, INERT MATL
(SAND, (SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT BRTHE VAPS. DO NOT GET IN EYES,
ON SKIN/ON CLTHG. WEAR PROT EQUIP &/OR GARMENTS DESCRIBED IN CTL
MEASURES IF EXPOS CNDTNS WARRANT.
Other Precautions:STORE IN COOL, WELL-VENT AREA AWAY FROM IGNIT
SOURCES. PROVIDE MEANS OF CONTROLLING LEAKS AND SPILLS. BOND AND
GROUND DURING LIQUID TRANSER. STORE BELOW -20F. KEEP CONTAINERS
CLOSED. AVOID UNNEC SKIN CONTAM W/MATL. NOTE:PERS PROT (ING 6)

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . NOT GENERALLY REQUIRED UNLESS NEEDED TO
PREVENT RESPIRATORY IRRITATION.
Ventilation:USE ADEQUATE VENTILATION TO CONTROL EXPOSURE BELOW
RECOMMENDED LEVELS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZS:EXPLO PEROXIDES WHEN EXPOSED TO AIR, ESP IF HEATED. EXPLAN
OF CARCIN:ANNUAL RPT ON CARCINS. 1994:ANTIC TO BE CARCIN.
ANIMAL:HEART, LUNGS, NOSE, SKIN. EFTS OF OVEREXP:ORGAN
TOXIN:HUMAN:GI & NERV TOXIN; SKIN HAZ:DERM. SPILL:CLAY, SAWDUST,
ETC.). TRANSFER TO DISPOSE DRUMS USING NON-SPARKING EQUIPMENT.

Vapor Density:>1
Solubility in Water:REACTS WITH WATER
Appearance and Odor:BLACK VISCOUS LIQUID WITH A PUNGENT ODOR.
Percent Volatiles by Volume:40

Stability Indicator/Materials to Avoid:YES
WATER, AIR, OXYGEN, STRONG OXIDIZING AGENTS AND COMBUSTIBLE MATERIALS.
Hazardous Decomposition Products:CARBON OXIDES FORMED WHEN BURNED.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . (INSURE CONFORMITY WITH ALL APPLICABLE DISPOSAL
REGULATIONS):CONTACT THE ENVIRONMENTAL COORDINATOR.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.